Binary hard sphere mixtures in block copolymer melts

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Binary hard sphere mixtures in block copolymer melts.

We perform a self-consistent-field/density-functional-theory hybrid analysis for a system of diblock copolymers mixed with polydisperse, hard, spherical particles of various chemical species. We apply this theory to study the equilibrium morphologies of two different binary sphere/diblock melts. First, we examine the case where the particles have two different sizes, but both types are preferen...

متن کامل

Universality of block copolymer melts.

Simulations of five different coarse-grained models of symmetric diblock copolymers are compared to demonstrate a universal (i.e., model-independent) dependence of the free energy and order-disorder transition (ODT) on the invariant degree of polymerization N̄. The actual values of χN at the ODT approach predictions of the Fredrickson-Helfand (FH) theory for N̄ ≳ 10(4) but significantly exceed FH...

متن کامل

Rescaled density expansions and demixing in hard-sphere binary mixtures.

The demixing transition of a binary fluid mixture of additive hard spheres is analyzed for different size asymmetries by starting from the exact low-density expansion of the pressure. Already within the second virial approximation the fluid separates into two phases of different composition with a lower consolute critical point. By successively incorporating the third, fourth, and fifth virial ...

متن کامل

Fluid-solid transitions on walls in binary hard-sphere mixtures

– We present measurements and theory of a fluid-solid phase transition at a hard, flat wall in a two-sized hard-sphere mixture. With particle concentrations well below the level for bulk phase separation, a fluid monolayer (enriched in the larger spheres) forms at the wall. At slightly higher concentrations, the wall-fluid freezes into a wall-solid phase which coexists with the bulk fluid. Meas...

متن کامل

Entropic Forces in Binary Hard Sphere Mixtures: Theory and Simulation

We perform extensive Monte Carlo simulations of binary hard-sphere mixtures (with diameter ratios of 5 and 10), to determine the entropic force between (1) a macrosphere and a hard wall, and (2) a pair of macrospheres. The microsphere background fluid (at volume fractions ranging from 0.1 to 0.34) induces an entropic force on the macrosphere(s); the latter component is at infinite dilution. We ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Physical Review E

سال: 2002

ISSN: 1063-651X,1095-3787

DOI: 10.1103/physreve.66.031801